| 摘 要： |
A novel Di-phase membrane device with DZ272 (DDD) containing a replenishing feed section and replenishing resolving section for the purification behavior of Co(II) has been studied. The replenishing feed section was composed of feed solution and Di-isooctylphosphinic acid (DZ272) as the carrier in fossil oil, and the replenishing resolving section was composed of DZ272 as the carrier in fossil oil and HCl as the resolving agent. The effects of the voluminal ratio of the membrane solution and feed solution (O/F), pH, initial molarity of Co(II) and ionic strength in the feed solution, voluminal ratio of membrane solution and resolving agent (O/S), molarity of H2SO4 solution and DZ272 molarity in the replenishing resolving section on purification of Co(II) were considered. The benefits of DDD compared to the traditional membrane device, system stability, reuse of the membrane solution and retention of the membrane section were also studied. Experimental results indicated that the optimal purification conditions of Co(II) were obtained, as H2SO4 molarity was 2.00 mol/L, DZ272 molarity was 0.120 mol/L, O/S was 3:1 in the replenishing resolving section, O/F was 1:8 and pH was 5.20 in the replenishing feed section. The ions intensity in the replenishing feed section had no apparent effect on purification behavior of Co(II). When the initial Co(II) molarity was 3.00 x 10(-4) mol/L, the purification percentage of Co(II) achieved 93.6% in 200 min. The kinetic equation was deduced in light of the law of mass diffusivity and interfacial chemistry. |
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