| 论文题目： | High-valent metals in advanced oxidation processes: A critical review of their identification methods, formation mechanisms, and reactivity performance |
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| 第一作者： | Yang Bowen, Liu Hongtao, Zhang Jun |
| 联系作者： | |
| 发表年度： | 2023 |
| 摘 要： | The role of high-valent metals as dominant reactive oxidants in advanced oxidation processes (AOPs) has not been systematically reviewed. The aim of this study was to provide an in-depth and comprehensive overview of high-valent metals in AOPs with respect to the identification methods, formation mechanisms, and reactivity performance. First, we discuss current identification methods for high-valent metals including their drawbacks. Subsequently, theoretical formation pathways and key influencing factors (e.g., pH and ligands) of high-valent metals are summarized. Based on density functional theory calculations, high-valent metals are more favor-able than radicals. We then compare high-valent metals with radicals with respect to their redox potential and reaction rate constant and observed that high-valent metals have a strong selectivity towards the electrophilic functional group due to their moderate oxidation performance. Finally, points for critical thinking and further prospects for high-valent metal-mediated oxidation processes are proposed. |
| 英文摘要： | |
| 刊物名称： | CHEMICAL ENGINEERING JOURNAL |
| 全文链接： | |
| 论文类别： | SCI |
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